![]() INTERNAL CLADDING FOR WIND TURBINES AND ASSEMBLY PROCEDURE (Machine-translation by Google Translate,
专利摘要:
Internal lining for wind turbine blades and its assembly procedure, the lining of which consists of a flexible wall sheath (5), which is made up of layers of composite materials, with shapes and dimensions approximately equal to those of the internal structural element (3) of the blade, the cover of which is mounted on a support (16), with which it is inserted into the blade. An inflatable chamber (18) is arranged between the support and cover, through which inflation compacts and adheres the cover against the internal surface of the structural element of the blade. (Machine-translation by Google Translate, not legally binding) 公开号:ES2827151A2 申请号:ES202130040 申请日:2016-12-13 公开日:2021-05-19 发明作者:De La Pena Razquin Emmanuel Garcia 申请人:Emprending Business S L; IPC主号:
专利说明:
[0002] INTERNAL COATING FOR WIND TURN BLADES AND [0004] Field of the invention [0006] The present invention refers to an internal lining for wind turbine blades, especially applicable to blades deteriorated by fatigue to which they have been subjected during the years of operation, and its purpose is to extend the life of the blades, beyond the life span useful for which they were designed. Another object of the invention is the method of mounting the cladding on a wind turbine blade. [0008] Background of the invention [0010] Wind turbine blades are typically designed to have a useful life of 20 years. This useful life is conditioned by the different compression and traction cycles to which the composite materials of the structural element of the blade are subjected (beam in blades manufactured by the procedure of pre-impregnation of fibers and resin, or its own reinforced shell in the case of paddles manufactured by the infusion procedure). These cycles of traction and compression, a consequence of the bending of the blade during the operation of the wind turbine, produce fatigue in said composite materials that lead to a fracture of the blade when the cycles for which it has been designed are exceeded. [0012] At present, when the blade exceeds the cycles for which it has been designed or in other words its useful life, it is replaced by a new one or another re-manufactured, whose remaining life justifies the cost of replacement. [0014] To solve the problem described, no other solution is known than to replace the blade that has reached the end of its useful life due to fatigue with a new one. [0016] There are systems to reinforce a specific area weakened by the existence of a design / manufacturing problem or by damage caused by an accident such as the described by ES2461390 where a system is defined to reinforce a weakened area of a wind turbine blade, which makes it possible to reinforce a weakened area of a wind turbine blade while the blade is mounted on the wind turbine. By means of this system, only the weakened area of the blade is reinforced, so that the rest of the blade remains unreinforced and, therefore, exposed to new weakened areas appearing when trying to prolong the life of the blade. [0018] On the other hand, the system object of ES2461390 is only applicable to blades with a beam-shell structure and not to infusion-type blades. [0020] According to the ES2461390 system, the reinforcements must be cured before being applied on the area of the blade to be reinforced, which causes adaptation problems on the surface to be reinforced and also requires motorized positioning equipment, for their introduction and transport through the blade, to the area where the reinforcement must be applied. [0022] Description of the invention [0024] The object of the present invention is to provide an internal lining for wind turbine blades, as well as the method of assembling it inside a wind turbine blade, to eliminate the aforementioned problems and to make it possible to reinforce the entire blade, thus ensuring prolonging its useful life. [0026] According to the invention, the lining consists of a flexible wall sheath, with shapes and dimensions approximately equal to those internal to the structural element of the blade for which said lining is intended, from root to tip, and open at its root. This cover is made up of pre-cut layers of composite fabrics, based on glass or carbon fibers and resins, uncured or only partially cured, which are applied, fixed and cured on the internal surface of the structural element of the blade. The cover can be made in one piece or in two longitudinal halves. [0028] According to another characteristic of the invention, the wall of the sheath extends, starting from the open root, in an external peripheral canal, like a neck. [0029] The procedure consists of applying the cover that constitutes the aforementioned coating inside a blade, on the structural element of the same, whose materials have lost their mechanical properties, due to the fact that they are already close or have exceeded their useful life. [0031] This sheath is added on the inner surface of the structural element of the blade, thus remaining adhered to surfaces degraded by fatigue, providing the blade as a whole with mechanical properties similar to those it originally had, allowing it to extend its life. of the same for a period of time sufficient to justify the cost of the intervention. [0033] In the case of blades made with pre-impregnated materials, the supplementary sleeve adheres to the internal faces of the beam that support the bending moments and that perform the function of a structural element (these faces are called CAPS). After adhering the extra cover to the CAPS, it will be this extra cover that performs the function of support and transmission of forces to the root of the blade and from there to the hub of the wind turbine. [0035] In the case of infusion-made blades, the cover will adhere to the internal faces of the reinforced shells, which in this type of technology act as a structural element and a transmission thread for the loads on the hub. [0037] The sections and materials of the cover will be calculated and designed to provide the blade with the mechanical properties necessary for its correct operation in optimal safety conditions, during the period of time that its life is extended. [0039] The cover is expected to be made of composite materials, fiberglass with resin or carbon fiber with resin. [0041] In the preferred embodiment, the cover, made of fiberglass or carbon, surrounds the interface of the blade root with the hub with a kind of neck, in the form of an external peripheral channel, which externally overlaps the wall of the blade in long enough to be traversed by the blade attachment bolts. This sheath will be of such dimension that it will cover the entire length of the blade, up to the tip or end of it. [0042] In accordance with the method of the invention, the flexible wall sheath is formed on a pre-forming mold, with shapes and dimensions approximately equal to the internal ones of the structural element of the blade, from the open root thereof to its end or tip. This cover is formed from layers of pre-cut fabrics of composite materials, preferably based on glass or carbon fibers and resins, uncured or only partially cured. [0044] On the other hand, the blasting and cleaning of the internal surface of the blade is carried out and the shaped cover is introduced therein. For this, the cover is mounted on a tool or support that is inserted with the cover inside the blade, through its open root, until it reaches the tip. Between the tool or support and the cover there is an inflatable chamber capable of reaching, through inflation, the internal volume of the structural element of the blade, with its shapes and dimensions, and is inserted into the blade. By pressurizing the inflatable chamber, the cover is compacted against the internal surface of the structural element of the blade, until said cover copies its internal shapes and adheres to it. [0046] Next, hot air is blown through the blade, until the composite materials that make up the cover are cured and hardened, as well as their adherence to the internal surface of the structural element of the blade. [0048] For the introduction and dragging of the tool or support through the blade, it is pulled with cables that are extracted through holes made in the tip or end of the blade and which are closed once the process is finished. [0050] Preferably, the sheath is finished at its open root in a neck, in the form of an external peripheral channel, which engages on the edge of the wall of the blade that limits the open root thereof, externally overlapping said wall by a sufficient length to be pierced by the tie bolts. [0052] The cover can be formed in a single piece or divided longitudinally into two or more parts that are inserted into the blade mounted on the tool or support, with interposition of the inflatable chamber, as described. [0053] The union of the cover to the internal surface of the structural element of the blade is achieved by the resin of the composite material that makes up the cover and, if necessary, with the addition of a reinforcing adhesive. [0055] As a preferred embodiment, you can use the inside of the blade itself that you want to extend the life of as a mold. For this, the process would begin with a blasting and cleaning operation of the interior of the structural element of the blade, to ensure a correct adhesive of the cover. Next, the pre-cut composite material fabrics, uncured or just pre-cured, but still flexible, would be introduced into the interior of the blade to be repaired, using cables, opening small holes in the tip. . Other tools or mounting brackets are possible. The pre-cut fabrics can be adhered to the internal surface of the structural element with their own resin or, if necessary, a reinforcing adhesive could be applied. [0057] Once this is done, the fabrics will be compacted by introducing an inflatable chamber or sleeve inside the blade, which will later be pressurized to achieve the correct compaction of the fabrics. Meanwhile, hot air is blown until complete cure and hardening of the composites. In this way it is achieved that the fabrics adhere to the contour of the interior of the structural element of the blade in the closest possible way, thus allowing a correct operation of the surfaces glued to shear, traction and compression. [0059] The placement of the extra cover will preferably be carried out in the wind farm, near the base of the wind turbine, to minimize special transports. [0061] In those blades that have a balancing block attached to the interior of the structural element, it will be necessary to remove said block before installing the coating object of this invention. [0063] This extraction will require the prior separation of the balancing block from the walls of the structural element of the blade, an operation that can be carried out by detaching the block by applying heat or by cutting the adhesive layer that joins the block with the surface of the structural element, and subsequent pulling of said plug for its extraction through the open root of the blade. [0064] Brief description of the drawings [0066] A non-limiting example of embodiment is shown in the attached drawings, in which: [0067] - Figure 1 shows a perspective view of a wind turbine blade. [0068] - Figure 2 a longitudinal section of the same blade, according to the cut line II-II of figure 1. [0069] - Figure 3 is a section similar to figure 2, showing a phase of blasting and cleaning the internal surface of the blade. [0070] - Figure 4 shows in perspective a possible embodiment of a cladding in the form of a sleeve divided into two parts for a wind turbine blade. [0071] - Figure 5 shows in perspective the pre-forming mold used in the formation of the sleeve of Figure 4. [0072] - Figure 6 shows, in longitudinal section of the blade, the assembly phase of the cover inside it. [0073] - Figure 7 is a view similar to Figure 6, where the sheath has been inserted up to the tip and the phase of compacting and joining of the sheath on the internal surface of the blade is shown. [0074] - Figure 8 shows a lateral section of a wind turbine blade similar to figure 2, incorporating in this case a balancing block glued to the beam on its inside face. [0075] - Figure 9 shows the balancing block in perspective, outside the blade, with its extraction tool. [0076] - Figure 10 is a schematic perspective of the complete tool for removing the balancing block. [0077] - Figures 11 to 14 show different stages of the extraction process of the balancing block, by applying heat. [0078] - Figures 15 and 16 show two successive stages of the extraction process of the balancing block, by cutting the layer of glue that joins said block to the beam. [0079] - Figures 17 and 18 show a possible variant of execution of the process of extracting the balancing block by applying heat. [0081] Detailed description of the invention [0082] The characteristics of the invention can be better understood with the following description of the embodiment shown in the above-listed drawings. [0084] Figures 1 and 2 show a wind turbine blade, open at its root (2), of the type made with pre-impregnated composite materials (usually glass or carbon fiber with an epoxy resin), and composed of a structural element (3), called a beam, and a shell (4). [0086] The method of the invention is based on the placement of a reinforcement sleeve inside the blade, which in the case of blades made with pre-impregnated materials will adhere to the internal faces of the structural element (3) or beam that support the bending moments. In the case of infusion blades, the cover will adhere to the internal surfaces of the reinforced shells. [0088] Figure 4 shows a sheath (5) for the stated purpose, divided longitudinally into two parts (6 and 7), each of which is obtained in a pre-forming mold (8), figure 5, by means of layers of fabrics. precut of composite materials. The sleeve (5) also has its root (9) open and adjacent to this open root, the wall of the sleeve is prolonged forming an external peripheral channel (10). [0090] The cover (5) is introduced into the blade (1) through its open root (2) and is coupled and fixed to the internal surface of the structural element (3). [0092] Before mounting the cover (5) on the blade (1), the internal surface of the structural element thereof is cleaned, an operation that can be carried out with a tool (11), figure 3, which incorporates nozzles. blasting (12) and cleaning (13). This tool can be inserted into the blade (1) by pulling with cables (14) that are extracted through holes (15) made in the tip of the blade (1). [0094] For the coupling of the sheath (5) inside the blade (1), the parts (6 and 7) that make up said sheath are mounted on a tool or support (16), Figure 6, which can be inserted into the blade in a similar way to that described for the tool (11), that is, pulling with the cables (14) extracted through holes made near the tip of the blade (1). To facilitate this operation, the support or tool (16) may have wheels (17). Between the tool (16) and the parts (6 and 7) of the cover there is arranged an inflatable bag or chamber (18). [0095] Once the tool (16) has reached its correct position inside the blade, figure 7, the inflatable bag or chamber (18) is inflated, for example, by means of a compressor (19). With this operation it is achieved that the parts (6 and 7) of the sheath are compacted against the internal surface of the structural element (3) of the blade, until they are completely coupled on said surface. Finally, the fabrics that make up the parts (6 and 7) of the cover are cured, and their adherence to the internal surface of the blade. If necessary, a reinforcing adhesive can be used. [0097] This operation can be carried out by blowing hot air through the open root of the blade or by including electric heating blankets on the outside of the shells (4) in the area where they adhere to the structural element (3) or between the inflatable chamber (18) and the composite material fabrics that make up the cover (5) or the parts (6 and 7) of said cover. [0099] In the event that the cover is made up of two parts (6 and 7), once one of the parts (6 or 7) of the cover is mounted on the blade in the manner described, the blade (1) is rotated and Proceed in the same way for the assembly of the other part (7 or 6) of the cover. [0101] Finally, the holes (15) made to pull the cables (14) are closed. [0103] The sheath can be made up of one, two or more parts. [0105] In another embodiment, the inside of the blade itself to be reinforced could be used as a mold for forming the cover. [0107] The outer peripheral channel (10) of the sleeve, figure 4, is coupled on the edge of the wall of the blade adjacent to its open root (2), to be traversed by the connecting bolts of said blade to the hub of the rotor of the wind turbine. [0109] The cover that constitutes the reinforcement of the blade is also applicable to blades manufactured by infusion, where the structural element (beam) and the shell are fused into a single element. [0110] In beams (3) with a balancing block (21), figure 8, the balancing block (21) is attached to the inside of the beam (3) at a certain radius and with a preset weight so that the rotor is not unbalanced when to turn. [0112] To carry out the process of the invention, it will be necessary to first proceed to the extraction of the balancing block. The extraction of this block can be carried out by applying heat to the faces of the balancing block, until the degradation temperature of the adhesive that joins said block to the walls of the beam is exceeded, or by cutting the layer. of adhesive that joins the block to the walls of the beam. According to a possible embodiment, the extraction of the balancing block (21) by cutting the layer of adhesive that joins said block with the walls of the beam (3) can be carried out with a tool (22) such as that shown in the Figures 9 and 10, composed of a central rod (23) to one of whose ends are articulated arms (24) that can pivot between a folded position, shown by a solid line in Figure 9, and a deployed position, shown in a broken line in the same figure with reference (24 '). [0114] The tool with the folded arms (24) can pass through the central passage (25) of the balancing block (21). Once the arms (24) pass the cleat, they can be deployed to position (24 '). Then pulling the central rod (23) it is possible to extract the plug. [0116] Due to the fact that the balancing block (21) is attached to the internal surface of the beam (3), in order to extract said block it will be necessary to detach it from the beam beforehand. For this, with the tool (22), a set of spatulas (26) can be combined that are mounted around the central rod (23), with the ability to move along it, and define a contour equal to the inside of the beam (3 ), with a sharp edge (27) directed towards the arms (24). Behind the spatulas and related to them, there is arranged a hollow actuating cylinder (28) that reacts on a lock (20) integral with the rod (23) when the cylinder (28) is activated. For greater clarity, the process would have the following stages: [0118] 1. The stem (23) is inserted through the hole (25) until we can expand the arms (24) [0119] 2. The stem (23) is pulled until the arms open to position (24 ') and are in contact with the balancing block (21) [0120] 3. The locking assembly (20), the cylinder (28) and the spatula assembly (26) are approached until they make contact with the other face of the balancing block (21) [0121] 4. The lock (20) is activated so that it is integral with the stem (23) [0122] 5. The cylinder (28) is activated, whose plunger has a stroke equivalent to the thickness of the block [0123] 6. The cylinder plunger (28) pushes the spatulas (26) between the balancing block (21) and the inner face of the beam (3) until the adhesive that fixes said stud to the inner face of the beam breaks. [0125] To proceed with the extraction of the balancing block (21), the tool (22) is inserted through the passage (25) and the arms (24) are deployed to position (24 '). Next, the cylinder (28) is activated to move the set of spatulas (26) until they penetrate between the balancing block (21) and the internal surface of the beam (3), detaching the balancing block, situation from the which by pulling the central rod (23), with the arms (24 ') deployed, is dragged to said balancing block to the outside of the blade. [0127] The process of cutting the layer of glue that joins the balancing block (21) to the wall of the beam (3) can also be carried out as follows: [0129] 1. - Through holes (29-29 '), figure 11, are drilled in the vertices of one face of the balancing block (21) by means of an incandescent rod (30), a laser or any other method. [0131] 2. - A hole (31) is made in the tip of the blade. [0133] 3. - A rod (32) is inserted through the tip of the blade, figure 12, which passes through the block through one of the holes (29) made in step (1) [0135] 4. - The rod (32) is extracted through the root of the blade where a wire (33) with the ability to glow in a segment or section of the same is attached to it. [0136] 5. - The rod (32) is pulled in the direction "D" until one end of the wire (33) is extracted through the tip of the blade. [0138] 6. - The rod (32) is inserted from the root of the blade, the plug is passed through the other hole (29 ') until the rod (32) is extracted through the hole (31). [0140] 7. - The end of the thread (33) that we left loose at the tip of the blade in step 5 is attached to the rod (32). [0142] 8. - The rod (32) is pulled from the root to pass the thread (33) through the hole (29 '), figure 13. [0144] 9. - Once the block is surrounded by the wire on its upper face, the section of the wire that is between the holes (29 and 29 ') on the face of the block that is closest to the tip of the blade. [0146] 10. - Proceed to pull the ends of the wire (33) from the root towards the root and upwards so that the incandescent sector of the wire, figure 14, cuts the glue that joins the plug to the inside face of the beam. [0148] 11. - The process is repeated for the other three faces that join the plug to the beam. [0150] According to a possible variant of execution, the wire used to cut the glue is made up of a resistant wire (32 '), figure 15, for example, a nylon wire or wire, which incorporates knots (34) or abrasive crimped balls . [0152] Once the thread is installed as described in steps 1 to 8 of the previous method, a loop is formed joining the two ends and it is passed through the edge of a wheel or sheave (35) with notches to receive the knots or balls to that, by turning, a rotating loop is generated, as if it were a chain transmission. The wheel-axle assembly moves as the cut progresses and is kept taut by a drive (36), such as a spring, which guarantees that the loop is always taut and that the necessary friction is produced at the other end so that go cutting the glue layer. [0153] The cutting of the glue layer around the contour of the block can be carried out by using a laser that falls from the face of the block that is oriented towards the root of the blade. [0155] Finally, the separation of the balancing block (21) can be carried out by applying heat to the faces of said block in the following way. [0157] Heat is applied on two of the faces (37 and 38) directly through the upper and lower shell section of the beam walls, until the glue is heated sufficiently to achieve degradation. For the other two faces (39 and 40), slots (41) will be made in one of the shells to introduce heating plates (42) that will transmit the heat through the walls (39 and 40) of the beam until the glue for degradation, figure 17. [0159] Once the glue has degraded, the plug is removed by fixing it to an element that can be pulled from the root of the blade, such as a carriage (43) that incorporates a head with a screw or bolt (44) that is screwed on some of the through holes (25) that the balancing block has. Next, the carriage is pulled, from the open root of the blade, to extract it together with the block, as shown in figure 18. [0161] Residual glue residue can be removed by mechanical brushing or other cleaning methods with water or high-pressure solvent.
权利要求:
Claims (16) [1] 1. - Internal lining for wind turbine blades defined by a structural element (3) and a shell (4), said lining made up of fabrics or layers of composite materials, based on glass or carbon fibers and resins, uncured or only partially cured, characterized in that it consists of a flexible wall sheath (5), made up of composite materials based on glass or carbon fibers and resins, with shapes and dimensions approximately equal to internal ones of the structural element (3) of the shovel and open at its root. [2] 2. - Coating according to claim 1, wherein the cover (5) is longitudinally composed of at least two parts (6 and 7). [3] 3. - Coating according to previous claims, where the wall of the sheath extends, starting from the root (9), in a portion that is bent outwards, forming a neck or external peripheral channel, dimensioned to fit on the edge from the wall of the shovel. [4] 4. - Procedure for applying the internal coating object of claims 1 to 3 in a wind turbine blade, characterized in that it comprises: a) forming on a preforming mold (8) a sleeve (5) with a flexible wall, open at its root, using fabrics or pre-cut layers of composite materials based on glass or carbon fibers and resins, uncured or only partially cured , with shapes and dimensions approximately equal to the internal ones of the structural element (3) of the blade; b) Prepare the interior surface of the structural element (3) by introducing a tool (11) with blasting nozzles (12) and washing (13) to form a clean and rough surface that facilitates the adherence of the coating composed of the sleeves (5); c) mounting the cover (5) on a support or tool (16); d) arranging between the support or tool (16) and the cover (5) an inflatable chamber (18), capable of reaching the internal shapes and dimensions of the structural element (3) of the blade by means of its inflation; e) insert the support, with the cover and inflatable chamber, inside the structural element of the blade, through the open root (2) of the blade until it reaches the tip of the blade, and proceed to inflate the blade. inflatable chamber (18) until applying the cover on the internal surface of the structural element of the blade; f) Proceed to the curing and hardening of the composite materials that make up the cover (5) and their adherence to the internal surface of the structural element (3) of the blade. [5] 5. - Method according to claim 4, where an external peripheral channel (10) is formed in the root (9) of the sheath (5), as an extension of the wall of said sheath, which is coupled on the edge of the wall of the blade that limits the open root (2) thereof, the outer surface overlapping the blade wall in a sufficient length to be traversed by the blade attachment bolts. [6] 6. - Procedure according to claims 4 to 5, where the sheath is formed by at least two longitudinal parts (6, 7), joined together. [7] 7. - Procedure according to claims 4 to 6, where the tool or support (16), with the cover (5) or parts of the cover (6, 7) and the inflatable chamber (18), is dragged through the blade pulling by cables (14) that are extracted to the outside through holes (15) made in the tip of the blade. [8] 8. - Procedure according to claims 4 to 7, where the cover (5) is formed on the internal surface of the structural element (3) of the blade, on which the fabrics or layers that make up said cover (5) are applied and are compacted by means of the inflatable chamber (18), introduced into the blade through its open root (2). [9] 9. Process according to claims 4 to 8, where the attachment of the cover (5) to the inner surface of the blade is carried out by means of the adhesive that includes the composite materials that make up the fabrics or layers. [10] 10.- Method according to claims 4 to 9, wherein a reinforcing adhesive is also applied to join the cover (5) to the internal surface of the blade. [11] 11. - Procedure according to claims 4 to 10, where in blades whose structural element (3) has a balancing block (21), before introducing the support with the cover (5) and inflatable chamber (18) inside the element structural element (3) of the blade, the balancing block (21) is extracted from the interior of said structural element (3). [12] 12. - Procedure according to claim 4, where the curing and hardening of the composite materials that make up the cover (5) is carried out by blowing with hot air through the open root (2) of the blade. [13] 13. - Process according to claim 4, where the curing and hardening of the composite materials that make up the sheath (5) is carried out by means of electric heating blankets arranged between the inflatable chamber (18) and the composite material fabrics that make up said sheath (fifteen). [14] 14. - Procedure according to claim 4, where the curing and hardening of the composite materials that make up the sheath (5) is carried out by means of electric heating blankets arranged on the shells (4) in the area of adherence to the structural element (3) . [15] 15. - Procedure according to claim 11, where the extraction of the balancing block (21) is carried out by detaching it from the internal surface of the structural element (3) of the blade, by applying heat to the faces of said block ( 21), and pulling the plug (21) through the open root (2) of the blade. [16] 16. - Procedure according to claim 11, where the extraction of the balancing block (21) is carried out by cutting the layer of adhesive that joins the balancing block (21) with the walls of the structural element (3) of the blade and subsequent pulling of said plug (21) through the open root (2) of the blade.
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同族专利:
公开号 | 公开日 ES2827151B1|2022-02-09| ES2827151R1|2021-05-21|
引用文献:
公开号 | 申请日 | 公开日 | 申请人 | 专利标题 FR2760681B1|1997-03-12|1999-05-14|Alternatives En|METHOD FOR MANUFACTURING A LARGE-DIMENSIONAL PART OF COMPOSITE MATERIAL AND PROPELLER BLADE, PARTICULARLY A WIND TURBINE, MANUFACTURED ACCORDING TO THIS PROCESS| US7963747B2|2009-04-02|2011-06-21|General Electric Company|Braided wind turbine blades and method of making same| US8753091B1|2009-05-20|2014-06-17|A&P Technology, Inc.|Composite wind turbine blade and method for manufacturing same| US20130216388A1|2012-02-20|2013-08-22|General Electric Company|Box-shaped shear web for wind turbine blades and method of making| US20130315747A1|2012-05-23|2013-11-28|Karsten Schibsbye|Wind turbine blade with improved geometry for reinforcing fibers|
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申请号 | 申请日 | 专利标题 ES202130040A|ES2827151B1|2016-12-13|2016-12-13|INTERNAL COATING FOR WIND TURBINE BLADES AND PROCEDURE FOR ASSEMBLING THE SAME|ES202130040A| ES2827151B1|2016-12-13|2016-12-13|INTERNAL COATING FOR WIND TURBINE BLADES AND PROCEDURE FOR ASSEMBLING THE SAME| 相关专利
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Process for preparation of 7 alpha-carboxyl 9, 11-epoxy steroids and intermediates useful therein an
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